Photocatalyst‐, Base‐ and Additive‐Free, Visible‐Light Induced 1,3‐Thiosulfonylation of Allylboronic Esters and Allylketones with Thiosulfonates.

  • Published In: Advanced Synthesis & Catalysis, 2025, v. 367, n. 12. P. 1 1 of 3

  • Database: Academic Search Ultimate 2 of 3

  • Authored By: Zheng, Xin; Yao, Tuanli; Wang, Kaiping; Zhang, Guodong; Zhang, Shuilong; Li, Xiang 3 of 3

Abstract

A practical and highly efficient radical 1,3‐thiosulfonylation of allylboronic esters and allylketones with thiosulfonates via 1,2‐functional group migration is described, affording diverse 1,3‐thiosulfonylated products in good yields. Notably, this method can be performed under photocatalyst‐, base‐ and additive‐free conditions, which features operational simplicity, high atom‐economy, excellent functional group tolerance and versatile transformations of the products. [ABSTRACT FROM AUTHOR]

Additional Information

  • Source:Advanced Synthesis & Catalysis. 2025/06, Vol. 367, Issue 12, p1
  • Document Type:Article
  • Subject Area:Chemistry
  • Publication Date:2025
  • ISSN:1615-4150
  • DOI:10.1002/adsc.202500051
  • Accession Number:186282981
  • Copyright Statement:Copyright of Advanced Synthesis & Catalysis is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

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